A single drop of a natural chiral ionic liquid (NCIL) serves as a wireless electrochemical microreactor for enantioselective synthesis. This system yields high selectivity (>90% ee) and demonstrates dynamic stereocontrol, where the enantiomeric excess is directly modulated by the external electric field. This catalyst-free strategy introduces a new paradigm for sustainable, tunable asymmetric reactions.
Tunable stereoselectivity in a wireless electrochemical microreactor using natural chiral ionic liquids / S. Grecchi, A. Mezzetta, L. Guazzelli, S. Arnaboldi. - In: GREEN CHEMISTRY. - ISSN 1463-9262. - 27:46(2025 Dec 14), pp. 14769-14775. [10.1039/d5gc04756k]
Tunable stereoselectivity in a wireless electrochemical microreactor using natural chiral ionic liquids
S. GrecchiPrimo
;S. Arnaboldi
Ultimo
2025
Abstract
A single drop of a natural chiral ionic liquid (NCIL) serves as a wireless electrochemical microreactor for enantioselective synthesis. This system yields high selectivity (>90% ee) and demonstrates dynamic stereocontrol, where the enantiomeric excess is directly modulated by the external electric field. This catalyst-free strategy introduces a new paradigm for sustainable, tunable asymmetric reactions.
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