We report enantioselective gold(I)-catalysed hydroarylation of alkynes to access inherently chiral calix[4]arenes. This method delivered a family of macrocycles, embedded with phenanthrene motifs, with good yields and enantioselectivities. Investigations of the photophysical and chiroptical properties revealed interesting fluorescence features, suggesting potential applications in materials science and devices.
Enantioselective Gold(I)-catalysed Alkyne Hydroarylations for Inherently Chiral Calix[4]arenes / M. Goudarzi, A. Alagiyawanna, A. Serafino, S. Rizzato, F. Bertocchi, F. Terenziani, S. Santoro, W. Qin, G. Cera, V. Pirovano. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - (2025), pp. 1-4. [Epub ahead of print] [10.1039/d5cc04405g]
Enantioselective Gold(I)-catalysed Alkyne Hydroarylations for Inherently Chiral Calix[4]arenes
M. GoudarziPrimo
;S. Rizzato;V. Pirovano
Ultimo
2025
Abstract
We report enantioselective gold(I)-catalysed hydroarylation of alkynes to access inherently chiral calix[4]arenes. This method delivered a family of macrocycles, embedded with phenanthrene motifs, with good yields and enantioselectivities. Investigations of the photophysical and chiroptical properties revealed interesting fluorescence features, suggesting potential applications in materials science and devices.
| File | Dimensione | Formato | |
|---|---|---|---|
|
d5cc04405g.pdf
accesso aperto
Tipologia:
Publisher's version/PDF
Licenza:
Creative commons
Dimensione
1.6 MB
Formato
Adobe PDF
|
1.6 MB | Adobe PDF | Visualizza/Apri |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
