Zeolitic Imidazolate Framework (ZIF-67) for recovery of polyphenols and Lead abatement from water

Owing to population growth and increasing industrialization, water pollution has become a critical global concern. Among the various water pollutants, polyphenols are often overlooked. However, they present a significant challenge: while polyphenols are widely recognized for their antioxidant properties, being beneficial in industries such as cosmetics, food, and nutraceuticals, their biorefractory nature makes them harmful when present in water at high concentrations. If not properly treated, polyphenols can harm biodiversity, disrupt ecological balance, and degrade water quality, posing risks to both the environment and human health [1]. Efficient removal and recovery of polyphenols are essential for sustainable water management and align with the circular economy’s goal of maximizing resource utilization.. Compounding this issue, heavy metals - ubiquitous in industries like mining, metal plating, and agriculture - add additional complexity. Persistent and non-biodegradable, heavy metals bioaccumulate in organisms, leading to severe health consequences such as organ toxicity and neurological disorders [2]. This study identifies the Zeolitic Imidazole Framework (ZIF-67), a Metal-Organic Framework (MOF), as a breakthrough material for addressing these dual challenges. ZIF-67 exhibits high adsorption capacity and excellent stability during repeated adsorption-desorption cycles, successfully recovering polyphenols like gallic acid from water. Moreover, the gallic acid-loaded ZIF-67 doubles as an effective adsorbent for secondary pollutants such as lead (Pb²⁺), with an impressive adsorption capacity of 1020 mg/g. The development of a ZIF-67-based filtration system offers a novel, sustainable solution for removing both polyphenols and heavy metals from water. This innovative approach extends the industrial applicability of MOFs, fostering cleaner water resources and advancing circular economy principles by integrating pollutant recovery with water purification. [1] A. Scalbert et al., Am. J. Clin. Nutr. 81 (2005) 215S-217S. [2] T. Deblonde et al., nt. J. Hyg. Environ., 214 (2011) 442-448. Keywords: Metal-organic frameworks, Adsorption, Polyphenols, Heavy metals, Water remediation.