Polymers can serve as an effective matrix to stabilize gold nanoparticles. These materials offer a continuous light-activated supply of subnanoclusters, which are composed of a few atoms. We report an efficient approach to enhance the catalytic activity of gold subnanoclusters by in situ feeding of these species through the generation of hot carriers via 5d-6s6p interband transitions on PEG-stabilized Au nanoparticles.
Visible light enhanced catalytic activity of Aun subnanoclusters: the importance of d–sp interband transitions / A. Sorroche, I. del-Campo, A. Casu, A. Falqui, M. Monge, J.M. López-de-Luzuriaga. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 60:63(2024 Aug 01), pp. 8204-8207. [10.1039/d4cc02370f]
Visible light enhanced catalytic activity of Aun subnanoclusters: the importance of d–sp interband transitions
A. CasuInvestigation
;A. FalquiInvestigation
;
2024
Abstract
Polymers can serve as an effective matrix to stabilize gold nanoparticles. These materials offer a continuous light-activated supply of subnanoclusters, which are composed of a few atoms. We report an efficient approach to enhance the catalytic activity of gold subnanoclusters by in situ feeding of these species through the generation of hot carriers via 5d-6s6p interband transitions on PEG-stabilized Au nanoparticles.
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