Triimidazo[1,2-a:1’,2’-c:1”,2”-e][1,3,5]triazine, is a molecule which has been studied by Cariati et. al. since 2017. This system possesses both Aggregation Induced Emission (AIE) and Room Temperature Ultralong Phosphorescence (RTUP) properties, whose discovery fueled further derivatization of the core: in fact, bio-active products, metal complexes and coordination polymers (CP), and phosphorescent organic emitters were synthesized and characterized. My work focused on a further derivatization of the TT scaffold with selected pendants, aiming at obtaining RTP materials and suitable ligands to be employed in luminescent metal complexes and coordination polymers.
NEW ORGANIC AND HYBRID INORGANIC/ORGANIC LUMINESCENT MATERIALS / D. Maver ; tutor: E. Cariati ; co-tutor: A. Colombo ; coordinatore: D. Roberto. - Via Golgi 19, Milano. Dipartimento di Chimica, 2025 Feb 04. 37. ciclo, Anno Accademico 2024/2025.
NEW ORGANIC AND HYBRID INORGANIC/ORGANIC LUMINESCENT MATERIALS
D. Maver
2025
Abstract
Triimidazo[1,2-a:1’,2’-c:1”,2”-e][1,3,5]triazine, is a molecule which has been studied by Cariati et. al. since 2017. This system possesses both Aggregation Induced Emission (AIE) and Room Temperature Ultralong Phosphorescence (RTUP) properties, whose discovery fueled further derivatization of the core: in fact, bio-active products, metal complexes and coordination polymers (CP), and phosphorescent organic emitters were synthesized and characterized. My work focused on a further derivatization of the TT scaffold with selected pendants, aiming at obtaining RTP materials and suitable ligands to be employed in luminescent metal complexes and coordination polymers.File | Dimensione | Formato | |
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phd_unimi_R13524.pdf
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