In this study, we report the synthesis and photocatalytic performance of Co₃O₄-decorated hexagonal boron nitride (hBN) composites for degrading methylene blue (MB) and ibuprofen (IBF) under sunlight irradiation. Using a dry impregnation method, the composites were prepared with varying Co₃O₄ loadings (0.5%, 1%, 2%). Comprehensive characterization confirmed the successful incorporation and uniform distribution of Co₃O₄ on the hBN matrix. Photocatalytic experiments revealed that 1% Co₃O₄-hBN composite exhibited the highest activity, achieving nearly 100% MB degradation in 60 min and 90% IBF degradation in 120 min. The enhanced photocatalytic efficiency is attributed to the synergistic effects between Co₃O₄ and hBN, which extend light absorption and promote charge separation. Our findings demonstrate the potential of Co3O₄-decorated hBN composites as effective photocatalysts for environmental remediation. The study provides a foundation for further exploration of these materials, including their long-term stability and application to a broader range of pollutants.

Synergistic photocatalytic degradation of methylene blue and ibuprofen using Co₃O₄-Decorated hexagonal boron nitride (hBN) composites under Sun-like irradiation / M. Bouziani, A. Bouziani, A. Hsini, C.L. Bianchi, E. Falletta, A. Di Michele, G. Çelik, R. Hausler. - In: CHEMOSPHERE. - ISSN 0045-6535. - 371:(2025 Feb), pp. 144061.1-144061.12. [10.1016/j.chemosphere.2025.144061]

Synergistic photocatalytic degradation of methylene blue and ibuprofen using Co₃O₄-Decorated hexagonal boron nitride (hBN) composites under Sun-like irradiation

C.L. Bianchi;E. Falletta;
2025

Abstract

In this study, we report the synthesis and photocatalytic performance of Co₃O₄-decorated hexagonal boron nitride (hBN) composites for degrading methylene blue (MB) and ibuprofen (IBF) under sunlight irradiation. Using a dry impregnation method, the composites were prepared with varying Co₃O₄ loadings (0.5%, 1%, 2%). Comprehensive characterization confirmed the successful incorporation and uniform distribution of Co₃O₄ on the hBN matrix. Photocatalytic experiments revealed that 1% Co₃O₄-hBN composite exhibited the highest activity, achieving nearly 100% MB degradation in 60 min and 90% IBF degradation in 120 min. The enhanced photocatalytic efficiency is attributed to the synergistic effects between Co₃O₄ and hBN, which extend light absorption and promote charge separation. Our findings demonstrate the potential of Co3O₄-decorated hBN composites as effective photocatalysts for environmental remediation. The study provides a foundation for further exploration of these materials, including their long-term stability and application to a broader range of pollutants.
Co3O4; hBN; Nanocomposite; Sunlight irradiation; Degradation; methylene blue; Ibuprofen
Settore CHEM-04/A - Chimica industriale
feb-2025
8-gen-2025
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/1131315
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