Enantioselectivities up to 75% have been found in the catalytic mono-oxidation of di-tert-butyl disulfide and related compounds as well as of ketene-S,S-acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined.

Enantioselective synthesis of thiosulfinates and of acyclic alkylidenemethylene sulfide sulfoxides / Stefano Colonna, Vincenza Pironti, Jozef Drabowicz, Franck Brebion, Louis Fensterbank, Max Malacria. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 2005:9(2005), pp. 1727-1730. [10.1002/ejoc.200400892]

Enantioselective synthesis of thiosulfinates and of acyclic alkylidenemethylene sulfide sulfoxides

S. Colonna;V. Pironti;
2005

Abstract

Enantioselectivities up to 75% have been found in the catalytic mono-oxidation of di-tert-butyl disulfide and related compounds as well as of ketene-S,S-acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined.
Asymmetric synthesis; Bovine serum albumin; Chiral dioxirane; Enantioselectivity; Thiosulfinate
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/10681
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