GrafeoPlad-Pd, a new metal-organic alloy comprised of Pd nanoparticles doped with 3D-entrapped graphene oxide, has promising applicative potential in sustainable synthetic organic chemistry. Besides hydrogenation, the metal nanopowder comprising the material is also active and relatively stable in cross-coupling reactions carried out consecutively. X-ray photoelectron spectroscopy (XPS) surface investigation and density functional theory (DFT) calculations are applied to gain new insight into the structure and potential new catalytic activity of this new class of molecularly doped metals.

GrafeoPlad Palladium: Insight on Structure and Activity of a New Catalyst Series of Broad Scope / M. Formenti, M.P. Casaletto, G. Barone, M. Pagliaro, C. Della Pina, V. Butera, R. Ciriminna. - In: ADVANCED SUSTAINABLE SYSTEMS. - ISSN 2366-7486. - 8:4(2024), pp. 2300643.1-2300643.8. [10.1002/adsu.202300643]

GrafeoPlad Palladium: Insight on Structure and Activity of a New Catalyst Series of Broad Scope

M. Formenti
Primo
;
C. Della Pina
;
2024

Abstract

GrafeoPlad-Pd, a new metal-organic alloy comprised of Pd nanoparticles doped with 3D-entrapped graphene oxide, has promising applicative potential in sustainable synthetic organic chemistry. Besides hydrogenation, the metal nanopowder comprising the material is also active and relatively stable in cross-coupling reactions carried out consecutively. X-ray photoelectron spectroscopy (XPS) surface investigation and density functional theory (DFT) calculations are applied to gain new insight into the structure and potential new catalytic activity of this new class of molecularly doped metals.
GrafeoPlad; graphene oxide; molecularly doped metal; MORAL; palladium;
Settore CHIM/03 - Chimica Generale e Inorganica
Settore CHIM/02 - Chimica Fisica
Settore CHIM/06 - Chimica Organica
2024
17-mar-2024
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/1040454
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