In the last twenty years, electrochemistry and photochemistry have attracted a renewed and still uprising interest in organic synthesis. Two of the most simple and abundant reagents, electrons and photons, became the key players in synthetic chemistry as cornerstones of developing greener and sustainable chemical processes. An interesting strategy that recently emerged is the possibility of merging the two worlds in what is called ElectroPhotoChemistry (EPC). In particular, this review will focus on the most recent contributions in the field. The basic principles of EPC will be presented along with a discussion of the published works of the last few years. Electrophotochemical oxidation/reduction reactions will be discussed, including in this section the transformations of a C–H bond to a C-X (X: heteroatom). In the C–H activation chapter the formation of C–C bond, starting from a C–H bond, will be considered. Finally, the miscellaneous chapter includes examples which do not clearly belong to the previous categories.

Latest updates in ElectroPhotoChemical reactions / F. Medici, V. Chiroli, L. Raimondi, M. Benaglia. - In: TETRAHEDRON CHEM. - ISSN 2666-951X. - 9:(2024), pp. 100061.1-100061.14. [10.1016/j.tchem.2023.100061]

Latest updates in ElectroPhotoChemical reactions

F. Medici
Primo
;
V. Chiroli
Secondo
;
L. Raimondi
Penultimo
;
M. Benaglia
Ultimo
2024

Abstract

In the last twenty years, electrochemistry and photochemistry have attracted a renewed and still uprising interest in organic synthesis. Two of the most simple and abundant reagents, electrons and photons, became the key players in synthetic chemistry as cornerstones of developing greener and sustainable chemical processes. An interesting strategy that recently emerged is the possibility of merging the two worlds in what is called ElectroPhotoChemistry (EPC). In particular, this review will focus on the most recent contributions in the field. The basic principles of EPC will be presented along with a discussion of the published works of the last few years. Electrophotochemical oxidation/reduction reactions will be discussed, including in this section the transformations of a C–H bond to a C-X (X: heteroatom). In the C–H activation chapter the formation of C–C bond, starting from a C–H bond, will be considered. Finally, the miscellaneous chapter includes examples which do not clearly belong to the previous categories.
Photocatalysis; Electrochemistry; Catalysis; Photoelectrochemistry; Organic synthesis
Settore CHIM/06 - Chimica Organica
2024
https://www.sciencedirect.com/science/article/pii/S2666951X2300027X
Article (author)
File in questo prodotto:
File Dimensione Formato  
PIIS2666951X2300027X.pdf

accesso aperto

Descrizione: Review Article
Tipologia: Publisher's version/PDF
Dimensione 1.87 MB
Formato Adobe PDF
1.87 MB Adobe PDF Visualizza/Apri
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/1029353
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 2
  • ???jsp.display-item.citation.isi??? ND
social impact