H-2, N-2, CO, and CO2 are readily incorporated in the porous, 3D sodalitic frameworks of coordination polymers of the [ML2](n) type, with M= Pd-II or Cu-II and HL= 2-hydroxypyrimidine or 4-hydroxypyrimidine. The metal ion and ligand functionalization modulate their sorption properties, making these materials suitable for gas storage and separation purposes.
H2, N2, CO, and CO2 sorption properties of a series of robust sodalite-type microporous coordination polymers / J. A. R. Navarro, E. Barea, J. M. Salas, N. Masciocchi, S. Galli, A. Sironi, C. O. Ania, J. B. Parra. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 45:6(2006), pp. 2397-2399.
H2, N2, CO, and CO2 sorption properties of a series of robust sodalite-type microporous coordination polymers
A. Sironi;
2006
Abstract
H-2, N-2, CO, and CO2 are readily incorporated in the porous, 3D sodalitic frameworks of coordination polymers of the [ML2](n) type, with M= Pd-II or Cu-II and HL= 2-hydroxypyrimidine or 4-hydroxypyrimidine. The metal ion and ligand functionalization modulate their sorption properties, making these materials suitable for gas storage and separation purposes.
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