The polar domains within model ionic liquids are assessed by intermolecular NOE interaction studies. The cation–cation distances in pure ionic liquids 1-butyl-3-methylimidazolium (see picture) and 1-butyl-2,3-dimethylimidazolium tetrafluoroborate are obtained and used to provide models of the local structure of the liquids.
The Local Structure of Ionic Liquids : Cation-Cation NOE Interactions and Internuclear Distances in Neat [BMIM][BF4] and [BDMIM][BF4] / A. Mele, G. Romanò, M. Giannone, E. Ragg, G. Fronza, G. Raos, V. Marcon. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 45:7(2006), pp. 1123-1126. [10.1002/anie.200503745]
The Local Structure of Ionic Liquids : Cation-Cation NOE Interactions and Internuclear Distances in Neat [BMIM][BF4] and [BDMIM][BF4]
E. Ragg;
2006
Abstract
The polar domains within model ionic liquids are assessed by intermolecular NOE interaction studies. The cation–cation distances in pure ionic liquids 1-butyl-3-methylimidazolium (see picture) and 1-butyl-2,3-dimethylimidazolium tetrafluoroborate are obtained and used to provide models of the local structure of the liquids.Pubblicazioni consigliate
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