The catalytic synthesis of high molecular weight aliphatic ketones by reductive condensation of lower molecular weight ketones was achieved by using CO in the presence of a multifunctional catalyst containing copper dispersed on alumina. The useful combination of condensation, water gas shift and hydrogenation reactions in a one-pot reaction allowed high yields of methylisobutylketone from acetone.
One-pot catalytic synthesis of higher aliphatic ketones / C. Della Pina, E. Falletta, M. Rossi, M. Gargano, P. Giannoccaro, R. Ciriminna, M. Pagliaro. - In: APPLIED CATALYSIS A: GENERAL. - ISSN 0926-860X. - 321:1(2007), pp. 35-39. [10.1016/j.apcata.2007.01.033]
One-pot catalytic synthesis of higher aliphatic ketones
C. Della PinaPrimo
;E. FallettaSecondo
;M. Rossi;
2007
Abstract
The catalytic synthesis of high molecular weight aliphatic ketones by reductive condensation of lower molecular weight ketones was achieved by using CO in the presence of a multifunctional catalyst containing copper dispersed on alumina. The useful combination of condensation, water gas shift and hydrogenation reactions in a one-pot reaction allowed high yields of methylisobutylketone from acetone.
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