Upon crystallization, [NBu4]2[Pt24(CO)48] self-assembles into infinite one-dimensional stacks of {Pt3(CO)6} units arranged in layers separated by [NBu4]+ ions. Close examination of the {Pt3(CO)6} stacks, which resemble CO-insulated platinum cables (see picture; CO ligands omitted), shows them to be composed of alternating blocks of seven {Pt3(CO)6} units and single {Pt3(CO)6} units.
Synthesis and Crystal Structure of [NBu4]2[Pt24(CO)48]: An infinite 1D Stack of [Pt3(CO)6]Units Morphologically Resembling a CO-Insulated Platinum Cable / C. Femoni, F. Kaswalder, M.C. Iapalucci, G. Longoni, M. Mehlstäubl, S. Zacchini, A. Ceriotti. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 45:13(2006), pp. 2060-2062.
Synthesis and Crystal Structure of [NBu4]2[Pt24(CO)48]: An infinite 1D Stack of [Pt3(CO)6]Units Morphologically Resembling a CO-Insulated Platinum Cable
A. CeriottiUltimo
2006
Abstract
Upon crystallization, [NBu4]2[Pt24(CO)48] self-assembles into infinite one-dimensional stacks of {Pt3(CO)6} units arranged in layers separated by [NBu4]+ ions. Close examination of the {Pt3(CO)6} stacks, which resemble CO-insulated platinum cables (see picture; CO ligands omitted), shows them to be composed of alternating blocks of seven {Pt3(CO)6} units and single {Pt3(CO)6} units.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
