The mechanism of dissociative electron transfer (ET) to a series of organic chlorides has been investigated both at an inert electrode and at a catalytic surface such as Ag; electrocatalysis is important only when breaking of the carbon-halogen bond is concerted with the ET.
Relevance of electron transfer mechanism in electrocatalysis : the reduction of organic halides at silver electrodes / A.A. Isse, L. Falciola, P.R. Mussini, A. Gennaro. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 2006:3(2006), pp. 344-346.
Relevance of electron transfer mechanism in electrocatalysis : the reduction of organic halides at silver electrodes
L. FalciolaSecondo
;P.R. MussiniPenultimo
;
2006
Abstract
The mechanism of dissociative electron transfer (ET) to a series of organic chlorides has been investigated both at an inert electrode and at a catalytic surface such as Ag; electrocatalysis is important only when breaking of the carbon-halogen bond is concerted with the ET.
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