The application of reductive carbonylation of nitroarenes to the synthesis of fine chemicals is described. The review focuses on the results reported from 1996 onwards and is mainly divided in two parts, respectively describing the intra-molecular cyclization reactions of nitroarenes bearing in the ortho position a suitable functional group and the intermolecular reactions of nitroarenes with external olefins and alkynes. Benzo-fused heterocycles such as indoles and quinolinones are obtained by the first group of reactions, whereas allylic amines, oxazines, pyrroles and indoles are the products of inter-molecular reactions. Mechanistic studies are also discussed in a separate section.
Fine chemicals by reductive carbonyllation of nitroarenes, catalyzed by transition metal complexes / F. Ragaini, S. Cenini, E. Gallo, A. Caselli, S. Fantauzzi. - In: CURRENT ORGANIC CHEMISTRY. - ISSN 1385-2728. - 10:12(2006), pp. 1479-1510.
Fine chemicals by reductive carbonyllation of nitroarenes, catalyzed by transition metal complexes
F. RagainiPrimo
;S. CeniniSecondo
;E. Gallo;A. CaselliPenultimo
;S. FantauzziUltimo
2006
Abstract
The application of reductive carbonylation of nitroarenes to the synthesis of fine chemicals is described. The review focuses on the results reported from 1996 onwards and is mainly divided in two parts, respectively describing the intra-molecular cyclization reactions of nitroarenes bearing in the ortho position a suitable functional group and the intermolecular reactions of nitroarenes with external olefins and alkynes. Benzo-fused heterocycles such as indoles and quinolinones are obtained by the first group of reactions, whereas allylic amines, oxazines, pyrroles and indoles are the products of inter-molecular reactions. Mechanistic studies are also discussed in a separate section.File | Dimensione | Formato | |
---|---|---|---|
33) Curr.Org.Chem.pdf
accesso riservato
Tipologia:
Publisher's version/PDF
Dimensione
306.56 kB
Formato
Adobe PDF
|
306.56 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.