Methanol was used as hydrogen source to reduce organic substrates, like alkynes, alkenes, nitro compounds and unsaturated ketones, in the presence of a supported copper catalyst. The detection of H-2, CO and HCOOCH3 in the reaction products allows us to postulate a mechanism for the hydrogen-transfer reaction based on a two-step dehydrogenation of methanol.
CATALYTIC HYDROGEN-TRANSFER REDUCTION OF ORGANIC-MOLECULES WITH METHANOL AS HYDROGEN SOURCE / L. Prati, M. Rossi, M. Gargano, N. Ravasio. - In: GAZZETTA CHIMICA ITALIANA. - ISSN 0016-5603. - 122:6(1992), pp. 221-224.
CATALYTIC HYDROGEN-TRANSFER REDUCTION OF ORGANIC-MOLECULES WITH METHANOL AS HYDROGEN SOURCE
L. PratiPrimo
;M. RossiSecondo
;
1992
Abstract
Methanol was used as hydrogen source to reduce organic substrates, like alkynes, alkenes, nitro compounds and unsaturated ketones, in the presence of a supported copper catalyst. The detection of H-2, CO and HCOOCH3 in the reaction products allows us to postulate a mechanism for the hydrogen-transfer reaction based on a two-step dehydrogenation of methanol.
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