The ortho, meta and para mono substituted anilines R-C6H4NH2 (R = 4-Me, 3-Me, 2-Me, 4-Et, 2-Et, 4-Br, 3-Br 2-Br; 4-Cl, 3-Cl, 2-Cl,4-F, 4-Pr-i, 4-Bu-t) were catalytically oxidised by H2O2, in the presence of cis-Mo(O)(2)(acac)(2), (acacH = CH3C(O)CH2C(O)CH3), producing the corresponding C-nitroso derivatives, R-C6H4NO. High conversions and selectivities were obtained. (C) 2000 Elsevier Science B.V. 2000 rights reserved.
Catalytic synthesis of C-nitroso compounds by cis-Mo(O)(2)(acac)(2) / F. Porta, L. Prati. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - 157:1-2(2000), pp. 123-129.
Catalytic synthesis of C-nitroso compounds by cis-Mo(O)(2)(acac)(2)
F. Porta;L. Prati
2000
Abstract
The ortho, meta and para mono substituted anilines R-C6H4NH2 (R = 4-Me, 3-Me, 2-Me, 4-Et, 2-Et, 4-Br, 3-Br 2-Br; 4-Cl, 3-Cl, 2-Cl,4-F, 4-Pr-i, 4-Bu-t) were catalytically oxidised by H2O2, in the presence of cis-Mo(O)(2)(acac)(2), (acacH = CH3C(O)CH2C(O)CH3), producing the corresponding C-nitroso derivatives, R-C6H4NO. High conversions and selectivities were obtained. (C) 2000 Elsevier Science B.V. 2000 rights reserved.
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