A high-yield procedure is described for the preparation, from [M(CO)3Cl2]2 (M = Ru, Os) and aqueous NaOH, of the new water-soluble and air-stable species [Ru(CO)2Cl(OH)]n, [Ru(CO)2(OH)2]n, [Os(CO)3Cl-(OH)]2, and [Os(CO)3(OH)2]x (x = 2 or n).
New water-soluble ruthenium(II) and osmium(II) hydroxo carbonyl complexes / E. Cariati, E. Lucenti, M. Pizzotti, D. Roberto, R. Ugo. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 15:20(1996), pp. 4122-4124. [10.1021/om960248q]
New water-soluble ruthenium(II) and osmium(II) hydroxo carbonyl complexes
E. CariatiPrimo
;E. LucentiSecondo
;M. Pizzotti;D. RobertoPenultimo
;R. UgoUltimo
1996
Abstract
A high-yield procedure is described for the preparation, from [M(CO)3Cl2]2 (M = Ru, Os) and aqueous NaOH, of the new water-soluble and air-stable species [Ru(CO)2Cl(OH)]n, [Ru(CO)2(OH)2]n, [Os(CO)3Cl-(OH)]2, and [Os(CO)3(OH)2]x (x = 2 or n).
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