Treating a pyridine (py) solution of PdCl2(py)(2) with a tetrahydrofuran or diethyl ether solution of the amido Grignard reagent 2,6-(Pr2C6H3NH)-C-1(MgCl) afforded a dimeric palladium complex, containing two bridging amido groups, which has been structurally characterised.
Use of amido Grignard reagents in inorganic chemistry : Synthesis and crystal structure of anti-[Pd(Cl)(py)(mu-2,6-Pri2C6H3NH)](2) / F. Ragaini, S. Cenini, F. Demartin. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :17(1997), pp. 2855-2856.
Use of amido Grignard reagents in inorganic chemistry : Synthesis and crystal structure of anti-[Pd(Cl)(py)(mu-2,6-Pri2C6H3NH)](2)
F. RagainiPrimo
;S. Cenini
Secondo
;F. DemartinUltimo
1997
Abstract
Treating a pyridine (py) solution of PdCl2(py)(2) with a tetrahydrofuran or diethyl ether solution of the amido Grignard reagent 2,6-(Pr2C6H3NH)-C-1(MgCl) afforded a dimeric palladium complex, containing two bridging amido groups, which has been structurally characterised.
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