The new compound [(diphos)Rh(μ2-H)2IrH2(P{i-Pr}3)2] (II) (diphos 1 Ph2 PCH2 CH2 PPh2) was prepared from [Rh(diphos)(MeOH)2]+ and [IrH5(P{i-Pr}3)2] and characterized by NMR and X-ray methods.
A rhodium(I)—iridium(III) hydrido-bridged phosphine complex / A. Musco, R. Naegeli, L. M. Venanzi, A. Albinati. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 228:1(1982), pp. C15-C18. [10.1016/S0022-328X(00)86781-9]
A rhodium(I)—iridium(III) hydrido-bridged phosphine complex
A. AlbinatiUltimo
1982
Abstract
The new compound [(diphos)Rh(μ2-H)2IrH2(P{i-Pr}3)2] (II) (diphos 1 Ph2 PCH2 CH2 PPh2) was prepared from [Rh(diphos)(MeOH)2]+ and [IrH5(P{i-Pr}3)2] and characterized by NMR and X-ray methods.
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