The syntheses and interconversions of mixed iron-rhodium carbonyl clusters are described; a combination of X-ray analysis and multinuclear n.m.r. measurements allowed the structural characterisation of [FeRh 4(CO)15]2-, [FeRh5(CO) 16]-, and [Fe2Rh4(CO) 16]2-, which can all be obtained from the unstable cluster, [Fe2Rh(CO)x]- (x = 10 or 11).
Bimetallic Iron-Rhodium anionic carbonyl clusters [Fe2Rh(CO)x]- (x= 10 or 11), [FeRh4(CO)15]2-, [Fe2Rh4(CO)16]2- and [FeRh5(CO)16]- / A.Ceriotti, G.Longoni, M.Manassero, M.Sansoni, R.Della Pergola, B.T.Heaton, D.O.Smith. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 15(1982), pp. 886-887.
Bimetallic Iron-Rhodium anionic carbonyl clusters [Fe2Rh(CO)x]- (x= 10 or 11), [FeRh4(CO)15]2-, [Fe2Rh4(CO)16]2- and [FeRh5(CO)16]-.
A. CeriottiPrimo
;
1982
Abstract
The syntheses and interconversions of mixed iron-rhodium carbonyl clusters are described; a combination of X-ray analysis and multinuclear n.m.r. measurements allowed the structural characterisation of [FeRh 4(CO)15]2-, [FeRh5(CO) 16]-, and [Fe2Rh4(CO) 16]2-, which can all be obtained from the unstable cluster, [Fe2Rh(CO)x]- (x = 10 or 11).
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