We studied the behaviour of bicyclic mesoionic compounds derived from the cyclodehydration of cyclic N-acyl-α-aminoacids 1-4 with N- (phenylmethylene)benzenesulfonamide 5. The reaction affords spirocyclic β- lactams and/or imidazo-condensed products (the 1,3-dipolar cycloaddition adducts) depending on the experimental conditions and on the nature of the substituent R on the mesoionic ring.
Reaction of mesoionic compounds deriving from cyclic N-acyl-alpha-aminoacids with N-(phenylmethylene)benzenesulfonamide / P. Dalla Croce, R. Ferraccioli, C. La Rosa. - In: TETRAHEDRON. - ISSN 0040-4020. - 55:1(1999), pp. 201-210.
Reaction of mesoionic compounds deriving from cyclic N-acyl-alpha-aminoacids with N-(phenylmethylene)benzenesulfonamide
P. Dalla CrocePrimo
;C. La RosaUltimo
1999
Abstract
We studied the behaviour of bicyclic mesoionic compounds derived from the cyclodehydration of cyclic N-acyl-α-aminoacids 1-4 with N- (phenylmethylene)benzenesulfonamide 5. The reaction affords spirocyclic β- lactams and/or imidazo-condensed products (the 1,3-dipolar cycloaddition adducts) depending on the experimental conditions and on the nature of the substituent R on the mesoionic ring.File in questo prodotto:
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