Decomposition of [PPN][Rh(CO)4] [PPN+ = (PPh3)2N+] at 200 °C under CO pressure affords [Rh(10)P(CO)(22)]3-, featuring the first decomposition reaction of PPN+ and explaining the reason for the deactivation of [PPN][Rh(CO)4]+-based catalytic systems.
Deactivation of a [PPN][Rh(CO)4]-based catalytic system [PPN+ = (PPh3)2N+]. The first decomposition reaction of PPN+ and the formation of [Rh10P(CO)22)]3 / F. Ragaini, A. Sironi, A. Fumagalli. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - :21(2000), pp. 2117-2118.
Deactivation of a [PPN][Rh(CO)4]-based catalytic system [PPN+ = (PPh3)2N+]. The first decomposition reaction of PPN+ and the formation of [Rh10P(CO)22)]3
F. RagainiPrimo
;A. SironiSecondo
;
2000
Abstract
Decomposition of [PPN][Rh(CO)4] [PPN+ = (PPh3)2N+] at 200 °C under CO pressure affords [Rh(10)P(CO)(22)]3-, featuring the first decomposition reaction of PPN+ and explaining the reason for the deactivation of [PPN][Rh(CO)4]+-based catalytic systems.
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