Starting from 3,5-dibromo-4-methoxy-phenylacetic acid methyl ester 2, a first total synthesis of the marine alkaloid polycitrin B is reported, based on the Pd catalyzed coupling reaction of the triflate 4 with the (4- methoxymethoxy-phenyl)tributylstannane. (C) 2000 Elsevier Science Ltd.
First total synthesis of the alkaloid polycitrin B / E.M. Beccalli, F. Clerici, A. Marchesini. - In: TETRAHEDRON. - ISSN 0040-4020. - 56:17(2000), pp. 2699-2702.
First total synthesis of the alkaloid polycitrin B
E.M. BeccalliPrimo
;F. ClericiSecondo
;A. MarchesiniUltimo
2000
Abstract
Starting from 3,5-dibromo-4-methoxy-phenylacetic acid methyl ester 2, a first total synthesis of the marine alkaloid polycitrin B is reported, based on the Pd catalyzed coupling reaction of the triflate 4 with the (4- methoxymethoxy-phenyl)tributylstannane. (C) 2000 Elsevier Science Ltd.
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