The novel anion [Rh9(CO)19]3-, obtained by condensation between the anions [Rh4(CO)11]2- and [Rh5(CO)15]-, contains a Rh9 metal-atom cluster formed by two condensed octahedra sharing a face.
Synthesis and x-ray structure of the anion [Rh9(μ 3-CO)3(μ-CO)9(CO)7]3- containing a cofacial bioctahedral rhodium cluster / S. Martinengo, A. Fumagalli, R. Bonfichi, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :15(1982), pp. 825-826.
Synthesis and x-ray structure of the anion [Rh9(μ 3-CO)3(μ-CO)9(CO)7]3- containing a cofacial bioctahedral rhodium cluster
G. CianiPenultimo
;A. SironiUltimo
1982
Abstract
The novel anion [Rh9(CO)19]3-, obtained by condensation between the anions [Rh4(CO)11]2- and [Rh5(CO)15]-, contains a Rh9 metal-atom cluster formed by two condensed octahedra sharing a face.
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