The unsaturated tetrahedral cluster {[Re-4(mu(3)-H)(4)(CO)(12)] in the presence of weak donor molecules L, like methanol or acetone, reversibly fragments to unsaturated triangular cluster anions and to mononuclear cations, probably via spiked-triangular [Re-4(mu-H)(4)(CO)(12)L(4)] intermediates.}
EASILY REVERSIBLE IONIC FRAGMENTATION OF A TETRAHEDRAL UNSATURATED RHENIUM CLUSTER, A REAPPRAISAL OF THE REACTION OF {[RE-4(MU(3)-H)(4)(CO)(12)] WITH METHANOL} / T. BERINGHELLI, G. D'ALFONSO. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :22(1994), pp. 2631-2632. [10.1039/c39940002631]
EASILY REVERSIBLE IONIC FRAGMENTATION OF A TETRAHEDRAL UNSATURATED RHENIUM CLUSTER, A REAPPRAISAL OF THE REACTION OF {[RE-4(MU(3)-H)(4)(CO)(12)] WITH METHANOL}
T. BeringhelliPrimo
;G. D'AlfonsoUltimo
1994
Abstract
The unsaturated tetrahedral cluster {[Re-4(mu(3)-H)(4)(CO)(12)] in the presence of weak donor molecules L, like methanol or acetone, reversibly fragments to unsaturated triangular cluster anions and to mononuclear cations, probably via spiked-triangular [Re-4(mu-H)(4)(CO)(12)L(4)] intermediates.}
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