The 5,7-diene system of ring B unsaturated steroids is transformed by neutral or alkaline permanganate mainly into a 5α,6α-dihydroxy-7α,8α-epoxide and minor amounts of more polar compounds.
Epoxidation of 7-double bond of cholesta-5,7-dien-3β-OL by permanganate / M. Anastasia, A. Fiecchi, A. Scala. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 20:35(1979), pp. 3323-3326. [10.1016/S0040-4039(01)95398-5]
Epoxidation of 7-double bond of cholesta-5,7-dien-3β-OL by permanganate
M. AnastasiaPrimo
;
1979
Abstract
The 5,7-diene system of ring B unsaturated steroids is transformed by neutral or alkaline permanganate mainly into a 5α,6α-dihydroxy-7α,8α-epoxide and minor amounts of more polar compounds.
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