The reaction of 2,3-isopropylidene-5-trityl-d-ribofuranose with methylenetriphenyl-phosphorane and the subsequent mercuriocyclization, iodomercuriation and Arbuzov reaction, allow a highly stereoselective entry to the phosphono analog of α-d-ribose 1-phosphate.
High stereoselective synthesis of diethyl (2,3-isopropylidene-5-trityl-α-d-ribofuranosyl)-methanephosphonate, a precursor to the phosphono analog of α-d-ribose 1-phosphate / F. Nicotra, L. Panza, F. Ronchetti, L. Toma. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 25:51(1984), pp. 5937-5938.
High stereoselective synthesis of diethyl (2,3-isopropylidene-5-trityl-α-d-ribofuranosyl)-methanephosphonate, a precursor to the phosphono analog of α-d-ribose 1-phosphate
F. RonchettiPenultimo
;
1984
Abstract
The reaction of 2,3-isopropylidene-5-trityl-d-ribofuranose with methylenetriphenyl-phosphorane and the subsequent mercuriocyclization, iodomercuriation and Arbuzov reaction, allow a highly stereoselective entry to the phosphono analog of α-d-ribose 1-phosphate.
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