The peculiar spongelike behavior of the nanoporous crystal, composed from the self-assembly of copper(II) sulfate and 1,3-bis(4-pyridyl)propane, is derived from its unusual topology: an architecture comprising two different structural motifs. The supramolecular catenation features ribbons- of-rings interpenetrating and entangling (4,4) layers.
Polymeric layers catenated by ribbons of rings in a three-dimensional self-assembled architecture: A nanoporous network with spongelike behavior / L. Carlucci, G. Ciani, M. Moret, D.M. Proserpio, S. Rizzato. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 39:8(2000), pp. 1506-+.
Polymeric layers catenated by ribbons of rings in a three-dimensional self-assembled architecture: A nanoporous network with spongelike behavior
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioPenultimo
;S. RizzatoUltimo
2000
Abstract
The peculiar spongelike behavior of the nanoporous crystal, composed from the self-assembly of copper(II) sulfate and 1,3-bis(4-pyridyl)propane, is derived from its unusual topology: an architecture comprising two different structural motifs. The supramolecular catenation features ribbons- of-rings interpenetrating and entangling (4,4) layers.
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