Boron enolates bearing menthone-derived chiral ligands are capable of fair to excellent diastereocontrol in their reactions with chiral aldehydes. Thioester-derived (better than ketone derived) enolates are able to control aldol stereochemistry irrespective of the aldehyde preferences.
REAGENT CONTROL IN THE ALDOL ADDITION-REACTION OF CHIRAL BORON ENOLATES WITH CHIRAL ALDEHYDES / C.M.A. GENNARI, D. MORESCA, A. VULPETTI, G. PAIN. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 35:26(1994), pp. 4623-4626. [10.1016/S0040-4039(00)60746-3]
REAGENT CONTROL IN THE ALDOL ADDITION-REACTION OF CHIRAL BORON ENOLATES WITH CHIRAL ALDEHYDES
C.M.A. GennariPrimo
;
1994
Abstract
Boron enolates bearing menthone-derived chiral ligands are capable of fair to excellent diastereocontrol in their reactions with chiral aldehydes. Thioester-derived (better than ketone derived) enolates are able to control aldol stereochemistry irrespective of the aldehyde preferences.
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