Several low loading supported catalysts were tested in the hydrogen transfer reduction of 4-tert-butyl-cyclohexanone showing good activity under very mild conditions (2-propanol as solvent, 83 C, N2). Results obtained by using different alcohols as donors suggest that a two step dehydrogenation-hydrogenation mechanism is operating over Cu/SiO2.
The use of copper catalysts in the hydrogen transfer reduction of 4-tert-butylcyclohexanone / F. Zaccheria, A. Fusi, R. Psaro, N. Ravasio - In: Catalysis of organic reactions / J.R.Sowa, Jr.. - [s.l] : CRC Press LLC, 2005. - ISBN 0-8247-2729-0. - pp. 293-301
The use of copper catalysts in the hydrogen transfer reduction of 4-tert-butylcyclohexanone
F. ZaccheriaPrimo
;A. FusiSecondo
;
2005
Abstract
Several low loading supported catalysts were tested in the hydrogen transfer reduction of 4-tert-butyl-cyclohexanone showing good activity under very mild conditions (2-propanol as solvent, 83 C, N2). Results obtained by using different alcohols as donors suggest that a two step dehydrogenation-hydrogenation mechanism is operating over Cu/SiO2.
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