A variety of chiral auxiliaries R*OH were prepared and tested for levels of asymmetric induction control in the "Mukaiyama-aldol" reaction of chiral silyl ketene acetals. Structural features required for high levels of control are discussed.
Auxiliary structure and asymmetric induction in the Mukaiyama-aldol reactions of chiral silyl ketene acetals / C. Gennari, F. Molinari, P. Cozzi, A. Oliva. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 30:38(1989), pp. 5163-5166. [10.1016/S0040-4039(01)93475-6]
Auxiliary structure and asymmetric induction in the Mukaiyama-aldol reactions of chiral silyl ketene acetals
C. GennariPrimo
;F. MolinariSecondo
;
1989
Abstract
A variety of chiral auxiliaries R*OH were prepared and tested for levels of asymmetric induction control in the "Mukaiyama-aldol" reaction of chiral silyl ketene acetals. Structural features required for high levels of control are discussed.
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