The crystal structure of the title compound, (C4H12N)-[Sb(C6H5) Cl-2(NCS)], contains two cations and two anions in the asymmetric unit. The Sb atom exhibits a distorted pseudo-trigonal -bipyramidal coordination, with the phenyl groups and the lone pair of electrons in equatorial positions and N-bonded thiocyanate and Cl- ligands in axial positions.
Tetramethylammonium chlorodiphenylthiocyanatoantimonate(III) / R. Artali, G. Bombieri, N. Bertazzi. - In: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. - ISSN 1600-5368. - 61:E61(2005), pp. m2733-m2735. [10.1107/S1600536805038870]
Tetramethylammonium chlorodiphenylthiocyanatoantimonate(III)
G. BombieriSecondo
;
2005
Abstract
The crystal structure of the title compound, (C4H12N)-[Sb(C6H5) Cl-2(NCS)], contains two cations and two anions in the asymmetric unit. The Sb atom exhibits a distorted pseudo-trigonal -bipyramidal coordination, with the phenyl groups and the lone pair of electrons in equatorial positions and N-bonded thiocyanate and Cl- ligands in axial positions.
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