Local trapping of excess electrons at the surface of solid water systems has recently been observed in large water clusters and at the ice/vacuum interface. The existence of stable surface-bound states for the excess electron may have important implications in atmospheric chemistry, electrochemistry, and radiation physics. By means of first-principles molecular dynamics we find that excess electrons induce a structural reconstruction of the ice surface on a time scale of a fraction of a picosecond. The surface molecular rearrangement leads to an increase of the number of dangling OH bonds pointing towards the vacuum and to the appearance of an electrostatic barrier preventing the penetration of the electron in the bulk. Both factors imply a remarkable stability for the surface-bound excess electron, with respect to its decay into the bulk solvated state.

Surface trapped excess electrons on ice / F. Baletto, C. Cavazzoni, S. Scandolo. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 95:17(2005), pp. 176801.1-176801.4. [10.1103/PhysRevLett.95.176801]

Surface trapped excess electrons on ice

F. Baletto
;
2005

Abstract

Local trapping of excess electrons at the surface of solid water systems has recently been observed in large water clusters and at the ice/vacuum interface. The existence of stable surface-bound states for the excess electron may have important implications in atmospheric chemistry, electrochemistry, and radiation physics. By means of first-principles molecular dynamics we find that excess electrons induce a structural reconstruction of the ice surface on a time scale of a fraction of a picosecond. The surface molecular rearrangement leads to an increase of the number of dangling OH bonds pointing towards the vacuum and to the appearance of an electrostatic barrier preventing the penetration of the electron in the bulk. Both factors imply a remarkable stability for the surface-bound excess electron, with respect to its decay into the bulk solvated state.
Settore FIS/03 - Fisica della Materia
2005
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/871337
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