Enzyme mechanisms: Using ab initio methods and natural bond orbital analysis, negative hyperconjugation is shown to govern L-lactate oxidation chemistry and may help to determine its enzymatic dehydrogenation mechanism. The picture shows the negative hyperconjugation interaction between the lone pair on the oxygen atom and the *(CH) orbital.
Does negative hyperconjugation assist enzymatic dehydrogenations? / G. Tabacchi, M.A. Vanoni, A. Gamba, E. Fois. - In: CHEMPHYSCHEM. - ISSN 1439-4235. - 8:9(2007 Jun 25), pp. 1283-1288.
Does negative hyperconjugation assist enzymatic dehydrogenations?
M.A. VanoniSecondo
;
2007
Abstract
Enzyme mechanisms: Using ab initio methods and natural bond orbital analysis, negative hyperconjugation is shown to govern L-lactate oxidation chemistry and may help to determine its enzymatic dehydrogenation mechanism. The picture shows the negative hyperconjugation interaction between the lone pair on the oxygen atom and the *(CH) orbital.
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