Natural ()-(7, 11)-Phytol (), a component of the chlorophyll molecule, vitamin K1 () and other natural compounds, was synthesized in enantiomerically and diastereomerically pure form by Li2CuCl4-induced coupling of two C10-units (, ). Both these units were prepared from geraniol () enzymatic enantioselective hydrogenation of activated double bonds.
Stereoselective total synthesis of natural phytol via double bond reductions by baker's yeast / P. Gramatica, P. Manitto, D. Monti, G. Speranza. - In: TETRAHEDRON. - ISSN 0040-4020. - 43:19(1987), pp. 4481-4486.
Stereoselective total synthesis of natural phytol via double bond reductions by baker's yeast
P. Manitto;G. Speranza
1987
Abstract
Natural ()-(7, 11)-Phytol (), a component of the chlorophyll molecule, vitamin K1 () and other natural compounds, was synthesized in enantiomerically and diastereomerically pure form by Li2CuCl4-induced coupling of two C10-units (, ). Both these units were prepared from geraniol () enzymatic enantioselective hydrogenation of activated double bonds.
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