A [copper(I)pyridine-containing ligand]-catalyzed reaCdon between 2-vinylindoles and,diazo esters is described. the reaction allows for the synthesis of a series of 2-vinylcyclopropa[b]indolines with excellent levels of regio- and sterocontrol under mild conditions.

[Copper(I)(Pyridine-Containing Ligand)] Catalyzed Regio- and Steroselective Synthesis of 2‑Vinylcyclopropa[b]indolines from 2‑Vinylindoles / V. Pirovano, E. Brambilla, G. Tseberlidis. - In: ORGANIC LETTERS. - ISSN 1523-7060. - 20:2(2018), pp. 405-408.

[Copper(I)(Pyridine-Containing Ligand)] Catalyzed Regio- and Steroselective Synthesis of 2‑Vinylcyclopropa[b]indolines from 2‑Vinylindoles

V. Pirovano
Primo
;
E. Brambilla
Secondo
;
G. Tseberlidis
Ultimo
2018

Abstract

A [copper(I)pyridine-containing ligand]-catalyzed reaCdon between 2-vinylindoles and,diazo esters is described. the reaction allows for the synthesis of a series of 2-vinylcyclopropa[b]indolines with excellent levels of regio- and sterocontrol under mild conditions.
Asymmetric cyclopropanation; stereoselective-synthesis; ethyl diazoacetate; CU(I) complexes; enantioselective synthesis; copper; indoles; heterocycles; derivatives; SILICA
Settore CHIM/06 - Chimica Organica
2018
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/543835
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