The solid-state structure of the beta-pinene allyl complex [Pd(eta(3)-C10H15)(1)]CF3SO3 (1, Josiphos = (Cp)Fe{C5H3(1-CH(CH3)PR21)-2-PR22}), R-1 = Cy, R-2 = Ph, has been determined by X-ray diffraction. The coordinated allyl is found to be rotated such that one allyl terminus is found almost in the P-Pd-P plane, whereas the second allyl terminus is approximately 0.37 Angstrom below this plane. This structural distortion is suggested to have an electronic, and not a steric origin.
Bonding of the beta-pinene allyl, eta(3)-C10H15 to Pd(II): X-ray structure of [Pd(eta(3)-C10H15)(Josiphos)]CF3SO3 / A. Albinati, P.S. Pregosin. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 296:1(1999 Dec), pp. 246-249.
Bonding of the beta-pinene allyl, eta(3)-C10H15 to Pd(II): X-ray structure of [Pd(eta(3)-C10H15)(Josiphos)]CF3SO3
A. AlbinatiPrimo
;
1999
Abstract
The solid-state structure of the beta-pinene allyl complex [Pd(eta(3)-C10H15)(1)]CF3SO3 (1, Josiphos = (Cp)Fe{C5H3(1-CH(CH3)PR21)-2-PR22}), R-1 = Cy, R-2 = Ph, has been determined by X-ray diffraction. The coordinated allyl is found to be rotated such that one allyl terminus is found almost in the P-Pd-P plane, whereas the second allyl terminus is approximately 0.37 Angstrom below this plane. This structural distortion is suggested to have an electronic, and not a steric origin.
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