Heterosubstituted aminoallenes underwent smooth ruthenium-catalyzed intramolecular exo-hydroamination reactions yielding the corresponding five-, six-, or seven-membered 1,3-diaza- or 1,3-oxaza-heterocyclic structures. This procedure is a valuable and less expensive alternative to the already known transition metal-catalyzed hydroamination reactions of aminoallenes.
Ruthenium-catalyzed hydroamination of aminoallenes: an approach to vinyl substituted heterocycles / G. Broggini, G. Poli, E.M. Beccalli, F. Brusa, S. Gazzola, J. Oble. - In: ADVANCED SYNTHESIS & CATALYSIS. - ISSN 1615-4150. - 357:4(2015 Feb 20), pp. 677-682.
Ruthenium-catalyzed hydroamination of aminoallenes: an approach to vinyl substituted heterocycles
E.M. Beccalli;
2015
Abstract
Heterosubstituted aminoallenes underwent smooth ruthenium-catalyzed intramolecular exo-hydroamination reactions yielding the corresponding five-, six-, or seven-membered 1,3-diaza- or 1,3-oxaza-heterocyclic structures. This procedure is a valuable and less expensive alternative to the already known transition metal-catalyzed hydroamination reactions of aminoallenes.
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