The NMR spectra of F19 and Cr53 have been obtained at low temperatures in a heterometallic substituted antiferromagnetic (AF) ring Cr7Cd with an S=3/2 ground state and compared with the spectra in a homometallic Cr8 AF ring with an S=0 ground state. From the analysis of the spectra one can derive directly model independent values of the staggered nonuniform distribution of the local moment in the heterometallic ring Cr7Cd. The experimental values are found to be in excellent agreement with the theoretical values calculated on the basis of an effective spin Hamiltonian which includes crystal field effects.
Local spin moment distribution in antiferromagnetic molecular rings probed by NMR / E. Micotti, Y. Furukawa, K. Kumagai, S. Carretta, A. Lascialfari, F. Borsa, G. A. Timco, and R. E. P.Winpenny. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 97:26(2006), pp. 267204.267204-1-267204.267204-4.
Local spin moment distribution in antiferromagnetic molecular rings probed by NMR
A. Lascialfari;
2006
Abstract
The NMR spectra of F19 and Cr53 have been obtained at low temperatures in a heterometallic substituted antiferromagnetic (AF) ring Cr7Cd with an S=3/2 ground state and compared with the spectra in a homometallic Cr8 AF ring with an S=0 ground state. From the analysis of the spectra one can derive directly model independent values of the staggered nonuniform distribution of the local moment in the heterometallic ring Cr7Cd. The experimental values are found to be in excellent agreement with the theoretical values calculated on the basis of an effective spin Hamiltonian which includes crystal field effects.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
