In the solid-state, the [RuH(arene)(Binap)]CF3SO3, complexes, 1, arene = eta(6)-benzene and 2, arene = eta(6)-toluene, distort markedly from a classical three-legged piano-stool structure with the former having the P-Ru-P plane approximately perpendicular to the plane of the arene; this structure for 1 is what one would expect for a transition state leading from one diastereomer to another via inversion at ruthenium.
Piano-stool inversion in arene complexes of Ru(II) : modelling the transition state / T. Geldbach, P. Pregosin, A. Albinati. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :12(2002), pp. 2419-2420.
Piano-stool inversion in arene complexes of Ru(II) : modelling the transition state
A. Albinati
2002
Abstract
In the solid-state, the [RuH(arene)(Binap)]CF3SO3, complexes, 1, arene = eta(6)-benzene and 2, arene = eta(6)-toluene, distort markedly from a classical three-legged piano-stool structure with the former having the P-Ru-P plane approximately perpendicular to the plane of the arene; this structure for 1 is what one would expect for a transition state leading from one diastereomer to another via inversion at ruthenium.File | Dimensione | Formato | |
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