The mass spectrometric behaviour of some carbonylrhodium(I) derivatives of 3,5-dimethyl- and 3,5-bis(trifluoromethyl)pyrazole (pz′H and pz″ H respectively) has been studied in detail by means of different ionization techniques (Electron Impact and Field Desorption), by recording the positive and negative ion mass spectra and by using linked scan methods for metastables. The species trans-(Ph3P)2(OC)Rh(pz″ -N) which showed an unexpected behaviour has been investigated by means of collision-al activation experiments. © 1983.
Positive and negative ion mass spectrometry of carbonylrhodium(I) derivatives of 3,5-dimethyl- and 3,5-bis(trifluoromethyl)pyrazole / P. Traldi, U. Vettori, G. Banditelli, A.L. Bandini, G. Minghetti. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 69:C(1983), pp. 207-214.
Positive and negative ion mass spectrometry of carbonylrhodium(I) derivatives of 3,5-dimethyl- and 3,5-bis(trifluoromethyl)pyrazole
G. Banditelli;A.L. BandiniPenultimo
;
1983
Abstract
The mass spectrometric behaviour of some carbonylrhodium(I) derivatives of 3,5-dimethyl- and 3,5-bis(trifluoromethyl)pyrazole (pz′H and pz″ H respectively) has been studied in detail by means of different ionization techniques (Electron Impact and Field Desorption), by recording the positive and negative ion mass spectra and by using linked scan methods for metastables. The species trans-(Ph3P)2(OC)Rh(pz″ -N) which showed an unexpected behaviour has been investigated by means of collision-al activation experiments. © 1983.
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