How can the entry into the area of chiral cationic alkyl derivatives of group 4 metals be simplified? We succeeded in, using readily available amino alcohols, which have been converted into chiral (hydroxyphenyl)oxazolines. These compounds have been employed in the organometallic derivatization of early transition metals.
(Hydroxyphenyl)oxazoline: a Novel and Remarkably Facile Entry into the Area of Chiral Cationic Alkylzirconium Complexes Which Serve as Polymerization Catalysts / P.G. Cozzi, E. Gallo, C. Floriani, A. Chiesi Villa, C. Rizzoli. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 14:11(1995), pp. 4994-4996.
(Hydroxyphenyl)oxazoline: a Novel and Remarkably Facile Entry into the Area of Chiral Cationic Alkylzirconium Complexes Which Serve as Polymerization Catalysts
E. GalloSecondo
;
1995
Abstract
How can the entry into the area of chiral cationic alkyl derivatives of group 4 metals be simplified? We succeeded in, using readily available amino alcohols, which have been converted into chiral (hydroxyphenyl)oxazolines. These compounds have been employed in the organometallic derivatization of early transition metals.
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