The heterobimetallic cyclosiloxanolate sandwich clusters Na{[η6-cyclo (PhSiO2)6]2[Fe(OR)]2Ni 4(μ6-Cl)} (R = H, Me) (1) were prepared from Na2{[(PhSiO2)6]2Na 4Ni4(OH)2} in the form of solvates. The new clusters 1 were characterized by spectra (UV-VIS, IR, 1H-NMR), cyclic voltammetry. conductivity, magnetic susceptibility, and single-crystal X-ray diffraction.
Heterobimetallic cyclosiloxanolate sandwich clusters: Na [6-cyclo(PhSiO2)6]2[Fe(OR)]2Ni4(6-Cl) (R=H. Me) / A. Cornia, A.C. Fabretti, G. Gavioli, C. Zucchi, M. Pizzotti, A. Vizi Orosz, O.I. Shchegolikhina, Y.U.A. Pozdniakova, G. Palyi. - In: JOURNAL OF CLUSTER SCIENCE. - ISSN 1040-7278. - 9:3(1998), pp. 295-319.
Heterobimetallic cyclosiloxanolate sandwich clusters: Na [6-cyclo(PhSiO2)6]2[Fe(OR)]2Ni4(6-Cl) (R=H. Me)
M. Pizzotti;
1998
Abstract
The heterobimetallic cyclosiloxanolate sandwich clusters Na{[η6-cyclo (PhSiO2)6]2[Fe(OR)]2Ni 4(μ6-Cl)} (R = H, Me) (1) were prepared from Na2{[(PhSiO2)6]2Na 4Ni4(OH)2} in the form of solvates. The new clusters 1 were characterized by spectra (UV-VIS, IR, 1H-NMR), cyclic voltammetry. conductivity, magnetic susceptibility, and single-crystal X-ray diffraction.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
