The surface chemistry of supported organometallic clusters as precursors of heterogeneous catalysts is investigated by means of DTG (differential thermal gravimetry) and TPOD (temperature-programmed oxidative decomposition) techniques, as unique signatures of the occurrence of chemical interactions between the organometallic cluster and the surface sites of the support.
TEMPERATURE-PROGRAMMED OXIDATIVE DECOMPOSITION (TPOD) TECHNIQUE FOR THE CHARACTERIZATION OF SUPPORTED METAL-CLUSTERS - A COMPARISON WITH DIFFERENTIAL THERMAL GRAVIMETRY (DTG) TECHNIQUE / C. DOSSI, A. FUSI, R. PSARO, D. ROBERTO. - In: THERMOCHIMICA ACTA. - ISSN 0040-6031. - 182:2(1991), pp. 273-280.
TEMPERATURE-PROGRAMMED OXIDATIVE DECOMPOSITION (TPOD) TECHNIQUE FOR THE CHARACTERIZATION OF SUPPORTED METAL-CLUSTERS - A COMPARISON WITH DIFFERENTIAL THERMAL GRAVIMETRY (DTG) TECHNIQUE
A. FUSISecondo
;R. PSAROPenultimo
;D. ROBERTOUltimo
1991
Abstract
The surface chemistry of supported organometallic clusters as precursors of heterogeneous catalysts is investigated by means of DTG (differential thermal gravimetry) and TPOD (temperature-programmed oxidative decomposition) techniques, as unique signatures of the occurrence of chemical interactions between the organometallic cluster and the surface sites of the support.
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