The structure of di-1,5-cyclooctadienesilver tetrafluoroborate was determined from single crystal X-ray diffraction data. The silver atom is four coordinated to the olefinic ends of the two cyclooctadiene molecules in a modified tetrahedral coordination described as "cubical". Bond lengths and other structural parameters are discussed and compared with the corresponding data found for other d10 and d8 olefin-metal complexes.
The crystal structure of the olefin complex di-1,5-cyclooctadienesilver tetrafluoroborate / A. Albinati, S. Meille, G. Carturan. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 182:2(1979), pp. 269-274.
The crystal structure of the olefin complex di-1,5-cyclooctadienesilver tetrafluoroborate
A. AlbinatiPrimo
;
1979
Abstract
The structure of di-1,5-cyclooctadienesilver tetrafluoroborate was determined from single crystal X-ray diffraction data. The silver atom is four coordinated to the olefinic ends of the two cyclooctadiene molecules in a modified tetrahedral coordination described as "cubical". Bond lengths and other structural parameters are discussed and compared with the corresponding data found for other d10 and d8 olefin-metal complexes.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
