Reaction of [Ni6(CO)12]2- with either C2Cl4 or C2Cl6 results in a direct synthesis for the new dicarbide cluster [Ni10(CO)16C 2]2-, which has been isolated and structurally characterized as its tetraphenylarsonium salt.
A NEW DIRECT SYNTHESIS FOR DICARBIDE CLUSTERS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [ASPH4]2[NI10(CO)16C2] / A. CERIOTTI, G. LONGONI, M. MANASSERO, N. MASCIOCCHI, L. RESCONI, M. SANSONI. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :4(1985), pp. 181-182.
A NEW DIRECT SYNTHESIS FOR DICARBIDE CLUSTERS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [ASPH4]2[NI10(CO)16C2]
A. CERIOTTIPrimo
;
1985
Abstract
Reaction of [Ni6(CO)12]2- with either C2Cl4 or C2Cl6 results in a direct synthesis for the new dicarbide cluster [Ni10(CO)16C 2]2-, which has been isolated and structurally characterized as its tetraphenylarsonium salt.File in questo prodotto:
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