O-Silylation of acylcobalt tetracarbonyls, RC(O)Co(CO)4, gives the dinuclear carbene complexes [μ2-RC(OSiR′3) (μ2-CO)Co2(CO)6], of which one derivative (R = Me, R′ = Ph) was characterized by X-ray diffraction.
O-silylation of acylcobalt tetracarbonyls: Synthesis of a new type of dinuclear μ2-hydroxycarbene cobalt carbonyl derivatives / A. Sisak, A. Sironi, M. Moret, C. Zucchi, F. Ghelfic, G. Pályi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :3(1991), pp. 176-178.
O-silylation of acylcobalt tetracarbonyls: Synthesis of a new type of dinuclear μ2-hydroxycarbene cobalt carbonyl derivatives
A. SironiSecondo
;
1991
Abstract
O-Silylation of acylcobalt tetracarbonyls, RC(O)Co(CO)4, gives the dinuclear carbene complexes [μ2-RC(OSiR′3) (μ2-CO)Co2(CO)6], of which one derivative (R = Me, R′ = Ph) was characterized by X-ray diffraction.
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