Approximately uniform size particles, corresponding to the dimension of the metallic skeleton of [Ni38Pt6(CO)48H] 5-, have been observed in the electron microscope at low beam intensities and electron energy loss spectroscopy (e.e.l.s.) is consistent with analytical data expected for this anion; at higher electron beam intensities particle agglomeration occurs together with formation of graphitic carbon and a face-centred cubic Ni/Pt alloy.
ANALYTICAL ELECTRON-MICROSCOPY OF [NI38PT6(CO)48H]5- / B. HEATON, P. INGALLINA, R. DEVENISH, C. HUMPHREYS, A. CERIOTTI, G. LONGONI, M. MARCHIONNA. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :10(1987), pp. 765-766.
ANALYTICAL ELECTRON-MICROSCOPY OF [NI38PT6(CO)48H]5-
A. CERIOTTI;
1987
Abstract
Approximately uniform size particles, corresponding to the dimension of the metallic skeleton of [Ni38Pt6(CO)48H] 5-, have been observed in the electron microscope at low beam intensities and electron energy loss spectroscopy (e.e.l.s.) is consistent with analytical data expected for this anion; at higher electron beam intensities particle agglomeration occurs together with formation of graphitic carbon and a face-centred cubic Ni/Pt alloy.Pubblicazioni consigliate
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