Sterically hindered chiral (salen)manganese complexes bearing long perfluoroalkyl substituents are synthesized and successfully employed as catalysts in the enantioselective (ee = 50-87%) epoxidation of alkenes under fluorous biphasic conditions.
Second-generation fluorous chiral (salen) manganese complexes / M Cavazzini, A. Manfredi, F. Montanari, S. Quici, G. Pozzi. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - :21(2000), pp. 2171-2172.
Second-generation fluorous chiral (salen) manganese complexes
A. ManfrediSecondo
;
2000
Abstract
Sterically hindered chiral (salen)manganese complexes bearing long perfluoroalkyl substituents are synthesized and successfully employed as catalysts in the enantioselective (ee = 50-87%) epoxidation of alkenes under fluorous biphasic conditions.
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